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08.08

Nanotechnology Holds Promise for Boosting Energy Efficiency

By Chris McManes

From rechargeable batteries to window coatings to high-capacity electrical wires, nanotechnology is increasingly being employed to make a wide array of products more energy efficient.

Congress was briefed on these new technology applications and their potential to improve America’s energy independence at a session hosted by the Congressional Nanotechnology Caucus in late July.

The event featured Dr. Wade Adams, director of the Richard E. Smalley Institute for Nanoscale Science and Technology at Rice University in Houston; Dr. Mark Pinto, chief technology officer at Applied Materials, Inc. in Santa Clara, Calif.; Joe Adiletta, senior product manager for A123Systems of Watertown, Mass.; and Douglas Kaempf, program manager, Industrial Technologies Program, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy (DOE).

Before we proceed, let’s define nanotechnology, and get a sense of the tiny space in which it operates. According to the IT encyclopedia Whatis.com, nanotechnology “is a branch of engineering that deals with the design and manufacture of extremely small electronic circuits and mechanical devices built at the molecular level.”

Nanotechnology takes its name from a nanometer one billionth of a meter. Most nanotechnology engineering is performed at 100 nanometers or less. National Geographic described the comparative size of a nanometer to a meter as the same as that of a marble to the size of the earth. A typical human hair is about 80,000 nanometers wide, and there are 25,400,000 nanometers in an inch.

Battery-Powered Vehicles

Before gasoline climbed to record-high prices this summer, General Motors and A123Systems began developing a rechargeable battery for GM’s electric drive E-Flex system. Based on A123Systems’ nanophosphate battery chemistry, the lithium-ion battery cells are going to be in the Chevy Volt, a plug-in hybrid electric vehicle that GM hopes to bring to market in late 2010.

The battery can be recharged simply by attaching it to a common 110-volt electrical plug. For those who drive less than 40 miles a day, the Volt will use no gasoline and produce no produce no harmful carbon emissions.

When compared to other lithium-ion battery chemistries, A123Systems’ nanophosphate-based cell technology provides higher power output, longer life and safer operations. It is built on nanoscale materials initially developed at the Massachusetts Institute of Technology.

A123Systems, founded in 2001, is the world’s largest manufacturer of batteries with nanophosphate chemistry. Most of the 10 million cells it produces each year are used in rechargeable power tools.

Adiletta told congressional staff members attending the briefing that consumer tax credits could help motivate drivers into purchasing plug-in hybrid electric vehicles.

“We believe that credits and incentives are critical to spur consumer adoption of the technology,” he said.

Moving Energy over Wire

Rice University’s Adams discussed how Dr. Richard Smalley who shared the 1996 Nobel Prize in Chemistry for discovering buckyballs (a one-nanometer form of carbon) was a leading advocate of the National Nanotechnology Initiative (NNI). Established in 2001, the NNI is the federal R&D program that coordinates multi-agency efforts in nanoscale science, engineering and technology. The initiative received a major boost when President Bush signed the 21st Century Nanotechnology Research and Development Act in December 2003.

Smalley was so well-respected by his Rice colleagues that the Smalley Institute for Nanoscale Science and Technology was named after him, following his death in 2005.

Adams related how Smalley came into the office one day in 2003 and said, “‘We need a new vision for energy for 2050, maybe even before that.’ And he called it the ‘distributed storage generation grid.’”

Smalley’s idea was to stop transporting energy as mass coal, oil, natural gas and start moving it by electricity over wire. He called this new conduction material, made entirely from metallic single-walled carbon nanotubes, “Armchair Quantum Wire.” NASA awarded Rice a four-year, $11-million contract in 2005 to produce a one-meter wire prototype by 2010.

In May 2005, Smalley described his Armchair Quantum Wire [www.hope.edu] as “a continuous cable of buckytubes that we expect will conduct electricity 10 times better than copper, yet have only one- sixth the weight, a zero coefficient of thermal expansion, and a tensile strength greater than steel.

“If we succeed, we’ll be able to rewire the world, replacing aluminum and copper in virtually every application, and permitting a vast increase in the capacity of the nation’s electrical grid. That and the development of plug-in electric hybrid vehicles will enable us to wean ourselves away from gasoline for the bulk of our urban transportation needs, free us from dependency on Middle East oil, and greatly improve the air quality in the cities throughout the world.”

Until the wire is perfected and manufactured on a large scale, Adams said the transition technology is the plug-in hybrid electric vehicle.

Nanomanufacturing Contributes to Energy Efficiency

Nanomanufacturing has the potential to contribute greatly to the United States’ major energy and climate initiatives. DOE estimates that applications in the chemicals, refining, maritime and automotive sectors alone could save up to 1.1 quadrillion BTU and prevent the emissions of more than 60 million metric tons of carbon dioxide annually. (In the United States, a quadrillion is 1,000 trillion).

“There’s a great benefit to nano,” the DOE’s Kaempf said. “For energy-efficient products, we’ve seen nano applications going into window coatings, lighting and lightweight vehicles. … And we want to improve fuel cells and supercapacitors. There are huge possibilities.

“With the energy gains, we do have to have the economic benefits. If you look at just the energy sector energy generation, storage and efficiency Lux Research is predicting that there will be over 20 billion dollars of goods produced with nanotechnology by 2012.”

Applied Materials’ Pinto discussed how his company uses nanomanufacturing technology to produce equipment, services and software products employed in fabricating semiconductor chips, energy-efficient glass, flat panel displays, solar photovoltaic cells and flexible electronics.

For example, Applied Materials’ low-emission, coated glass reduces solar heat increases in the summer and heat loss in the winter. This decreases a homeowner or business’ heating and cooling costs.

“This environmentally friendly glass pays for itself because of nanomanufacturing technology,” said Pinto, adding that the two largest markets for the product are China and the Middle East, areas undergoing a building boom.

Lighter Weight Equals Greater Fuel Efficiency

A123Systems’ Adiletta also talked about working with BAE Systems to develop an 800-pound battery for buses to replace a 4,000-pound battery. Trimming vehicle weight is key to increasing fuel efficiency.

“There’s a clear relationship between vehicle weight and fuel consumption,” Adams said. “If we go beyond thinking lightweight to thinking ultra-lightweight with nanocomposite technology, that’s how we’ll get there. And we are making progress.”

Despite these composites’ lighter weight, they are much stronger. Carbon nanotubes have twice the tensile strength of the best carbon fiber.

“In principle, if we can make the single-walled carbon nanotubes into these fibers, we can go up to factors of somewhere around 40,” Adams said. “So we could, in principle, make extremely strong composites, strong enough so that even a Texan in an SUV I have to hype on Texans can have as big a vehicle as we have today but could be very light and can use like one-eighth of the gasoline.

“And if you make it a plug-in hybrid, the gasoline consumption would be more like sipping gas.”

Role of the Department of Energy

The DOE conducts research & development to accelerate the scale-up and commercialization of nanomanufacturing technologies in the United States. It focuses on applied research at both its national labs and through cost-shared public/private partnerships to help move products to market in 3 to 5 years.

“Our goal is to work with industry and work with our national labs to try to get this technology to make a difference in consumers’ lives today,” said Kaempf, who earned a master’s in technology management from the University of Maryland and a bachelor’s in electrical engineering from Penn State.

The DOE’s Industrial Technologies Program has positioned itself to be the federal agency investing in the application side of nanotechnology.

“We leverage the significant investment in nanoscience and build the manufacturing capability to deliver products to the American people,” Kaempf said.

Lux Research, which provides strategic advice on emerging technologies, said the value of goods incorporating nanotechnology was $1.1 trillion in 2007. By 2015, it is expected to reach nearly $4 trillion. The federal government invested $1.4 billion in nanotechnology research in 2007. Other nations are increasingly investing more money in this area.

“There’s a huge opportunity here,” Kaempf said. “VCs (venture capitalists) see it, we see it, the world sees it.”

 

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Chris McManes is IEEE-USA's public relations manager. Comments may be submitted to todaysengineer@ieee.org.


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